A sol-gel route for the development of rare-earth aluminum borate nanopowders and transparent thin films |
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| Authors: | Lauro J.Q. Maia Valmor R. Mastelaro Antonio C. Hernandes |
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| Affiliation: | a Grupo Crescimento de Cristais e Materiais Cerâmicos, Instituto de Física de São Carlos-Universidade de São Paulo, Caixa Postal 369, 13560-970 São Carlos/SP, Brazil
b Laboratoire de Cristallographie, CNRS, UPR 5031, associé à l’Université Joseph Fourier-Grenoble et à l’INPG, 25 Avenue des Martyrs, BP 166, 38042 Grenoble, France |
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| Abstract: | A new sol-gel route was applied to obtain Y0.9Er0.1Al3(BO3)4 crystalline powders and amorphous thin films by using Al(acac)3, B(OPri)3, Y(NO3)3·6H2O, and Er(NO3)3·5H2O as starting materials dissolved in propionic acid and ethyl alcohol mixtures. Our study shows that propionic acid acts as good chelant agent for yttrium and erbium ions while ethyl alcohol allows to dissolve Al(acac)3. This process makes the resulting sols very stable to obtain homogeneous gels and transparent amorphous thin films. In addition, the propionic acid prevents the sol precipitation, making easy porous- and crack-free thin film depositions. Chemical reactions involved in the complexation were discussed. As-prepared powders and films are amorphous and present a good thermal stability due to their high glass transition (746 °C) and crystallization temperatures (830 °C). This new sol-gel route showed to be adequate to obtain dense and crack-free thin films free of organic and hydroxyl groups that can be considered as promising materials to be used in integrated optical systems. |
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| Keywords: | Sol-gel Propionic acid Y0.9Er0.1Al3(BO3)4 Nanopowders Thin films Thermal analyses XRD SEM FEG |
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