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反相流动注射-紫外光还原-分光光度法测定饮用水中的硝酸盐
引用本文:张敏,袁东星,冯思超,黄勇明. 反相流动注射-紫外光还原-分光光度法测定饮用水中的硝酸盐[J]. 分析化学, 2011, 39(6): 943-944. DOI: 10.3724/SP.J.1096.2011.00943
作者姓名:张敏  袁东星  冯思超  黄勇明
作者单位:厦门大学近海海洋环境科学国家重点实验室,厦门大学环境科学研究中心,厦门,361005
基金项目:国家"863"项目,"长江学者和创新团队发展"计划
摘    要:1引言硝酸盐广泛存在于各种环境水体中。当饮用水中硝酸盐浓度过高时,可能对人体健康造成危害;地表水中硝酸盐大量积累,则可能引起藻类过度繁殖,溶解氧耗竭,水质恶化。目前,检测硝酸盐的最常用方法是将硝酸盐还原为亚硝酸盐,再经重氮偶联反应后由分光光度法进行测定[1]。此类方法已较好地与流动分析技术相结合,广泛应用于测定环境样

关 键 词:Nitrate  ultraviolet-induced reduction  Flow injection  Spectrophotometry

Reversed Flow Injection Analysis of Nitrate in Drinking Water with UV-induced Reduction to Nitrite and Spectrophotometric Detection
ZHANG Min,YUAN Dong-Xing,FENG Si-Chao,HUANG Yong-Ming. Reversed Flow Injection Analysis of Nitrate in Drinking Water with UV-induced Reduction to Nitrite and Spectrophotometric Detection[J]. Chinese Journal of Analytical Chemistry, 2011, 39(6): 943-944. DOI: 10.3724/SP.J.1096.2011.00943
Authors:ZHANG Min  YUAN Dong-Xing  FENG Si-Chao  HUANG Yong-Ming
Affiliation:ZHANG Min,YUAN Dong-Xing*,FENG Si-Chao,HUANG Yong-Ming(State Key Laboratory of Marine Environmental Science,Environmental Science Research Center,Xiamen University,Xiamen 361005)
Abstract:An environmental friendly method was developed based on reversed flow injection(r-FIA) with UV-induced reduction of nitrate to nitrite and spectrophotometric detection.Sample or standard solutions were mixed with a phosphate buffer solution containing diethylenetriaminepentaacetate(DTPA),and then passed through a UV reduction reactor equipped with an 8 W low pressure mercury lamp,where the nitrate was reduced to nitrite.The formed nitrite was detected with spectrophotometric method through Griess reaction.L...
Keywords:Nitrate  ultraviolet-induced reduction  Flow injection  Spectrophotometry  
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