|
|||||
|
|
Ein dreikerniger Zinkkomplex mit ZnS4‐, ZnS3O‐ und ZnS2NO‐Koordinationen |
|
| Authors: | Astrid Schneider Heinrich Vahrenkamp |
| Abstract: | A Trinuclear Zinc Complex with ZnS4, ZnS3O, and ZnS2NO Coordinations The reaction between the tris(thioimidazolyl)borate complex [TttBuZn‐OClO3] and 2‐pyridylbenzylalcohol (PBAH) yields the compound[(TttBu)3Zn3(PBA)] (ClO4)2. In its trinuclear complex cation tris(thioimidazolyl)borate ligands, which adopt the umbrella conformation, bridge the zinc ions, which have the three different coordinations ZnS4, ZnS3O and ZnS2NO. |
| Keywords: | Zinc complexes Tripodal ligands Trinuclear Bridging ligands |