Reaktionen eines Dibismutans und von Cyclobismutanen mit Metallcarbonylen ‐ Synthesen von Komplexen mit R2Bi‐, RBi‐, Bi2‐ und Bin‐Liganden (R = Me3CCH2, Me3SiCH2) |
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| Authors: | L Balzs H J Breunig E Lork |
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| Institution: | L. Balázs,H. J. Breunig,E. Lork |
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| Abstract: | Reactions of a Dibismuthane and of Cyclobismuthanes with Metal Carbonyls ‐ Syntheses of Complexes with R2Bi‐, RBi‐, Bi2‐ and Bin‐ligands (R = Me3CCH2, Me3SiCH2) Reactions of Fe2(CO)9] with (Me3CCH2)4Bi]2 or cyclo‐(Me3SiCH2Bi)n (n = 3 ‐ 5) lead to the complexes (R2Bi)2Fe(CO)4], RBiFe(CO)4]2R = Me3CCH2, Me3SiCH2] and Bi2Fe3(CO)9]. Bi2{Mn(CO)2C5H4CH3}3] forms in a photochemical reaction of Mn(CO)3C5H4CH3] with cyclo‐(Me3SiCH2Bi)n. |
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| Keywords: | Bismuth Iron Manganese |
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