Synthesen und Molekülstrukturen von [Cu20Ga10Cl4Se23(PEt2Ph)12] und [Cu14In6Se7(iPrSe)18] |
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Authors: | Andreas Eichh fer,Dieter Fenske,Jolanta Olkowska‐Oetzel |
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Affiliation: | Andreas Eichhöfer,Dieter Fenske,Jolanta Olkowska‐Oetzel |
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Abstract: | Syntheses and Structures of [Cu20Ga10Cl4Se23(PEt2Ph)12] and [Cu14In6Se7(iPrSe)18] CuCl and GaCl3 react with Se(SiMe3)2 in thf solution to yield in the presence of PEt2Ph [Cu20Ga10Cl4Se23(PEt2Ph)12] ( 1 ). Reaction of CuCl, InCl3 and TMEDA with iPrSeSiMe3 in DME results in the crystallisation of [Cu14In6Se7(iPrSe)18] ( 2 ). The structures of 1 and 2 were determined by X‐ray single crystal structure analysis and display two new types of molecular clusters formed by the elements of group 11, 13, and 16. However, both cluster structures show no analogy to the structures of the related bulk phases. |
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Keywords: | Copper Group 13 elements Group 16 elements Cluster compounds |
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