Abstract: | A 2D grid‐shaped bimetallic imidazolate polymer CoIICuI2(Im)4];∞ ( 1 ) was solvothermally synthesized and characterized with single crystal X‐ray analysis: tetragonal space group P 21/c (No.114), a = b = 10.9513(15) Å, c = 6.3063(13) Å, V = 756.3(2) Å3. This is the first cobalt(II) imidazolate polymer hybridized with other transition metals. |