| AGNTO的制备和分子结构 |
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| 引用本文： | 杨利,张同来,冯长根,郁开北.AGNTO的制备和分子结构[J].物理化学学报,2001,17(5):438-442. |
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| 作者姓名： | 杨利 张同来 冯长根 郁开北 |
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| 作者单位： | Department of Mechano electric Engineering, Beijing Institute of Technology, Beijing 100081;Chengdu Branch, Chinese Science Academy, Chengdu 640041 |
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| 摘 要： | 通过3-硝基-1，2，4-三唑-5-酮（NTO）与氨基胍重碳酸盐反应制备NTO氨基胍盐，并用X射线衍射、元素分析、红外光谱对其进行了表征.晶体属于单斜晶系，空间群为P21/n.晶体学参数为：a=0.67870(10)nm， b=2.7915(4)nm， c=1.2739(2)nm； β =96.930(10) V=2.3959(6)nm3， Z=12， Dc=1.698 g•cm －3， μ( Mo K )=1.47 cm －1， F(000)=1272.晶体结构经全矩阵最小二乘法修正，最终偏离因子R=0.0352， wR =0.0718.该盐是一种具有广泛应用前景的产气剂材料.
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| 关 键 词： | 3-硝基-1，2，4-三唑-5-酮(NTO) 氨基胍重碳酸盐 分子结构 NTO氨基胍(AGNTO) |
| 收稿时间： | 2000-11-06 |
| 修稿时间： | 2000年11月6日 |
Preparation and Molecular Structure of AGNTO |
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| Yang Li,ZHANG Tong-lai,Feng Chang-Gen,Yu Kai-Bei.Preparation and Molecular Structure of AGNTO[J].Acta Physico-Chimica Sinica,2001,17(5):438-442. |
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| Authors: | Yang Li ZHANG Tong-lai Feng Chang-Gen Yu Kai-Bei |
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| Institution: | Department of Mechano electric Engineering, Beijing Institute of Technology, Beijing 100081;Chengdu Branch, Chinese Science Academy, Chengdu 640041 |
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| Abstract: | AGNTO was prepared by mixing amino-carbamidine bicarbonate and 3-nitro-1,2,4-triazol-5-one. The product was characterized by element analysis and IR measurement. The crystal structure of AGNTO was determined by single crystal diffraction analysis. The crystal belongs to monoclinic space group P21/n. Crystallographic data are:a=0.67870(10)nm， b=2.7915(4)nm， c=1.2739(2)nm； β =96.930(10)° ， V=2.3959(6)nm3， Z=12， Dc=1.698 g· cm－ 3， μ (Mo Kα )=1.47 cm－ 1， F(000)=1272, R=0.0352， wR=0.0718. This salt would be a very promising energetic material, and it might be used as new gas generate agent. |
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| Keywords: | 3-nitro-1 2 4-triazol-5-one(NTO) Amino-carbamidine bicarbonate Molecular structure Amino-carbamidine 3-nitro-1 2 4-triazol-5-one(AGNTO) |
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