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Mössbauer characterization of calcium–ferrite oxides prepared by calcining Fe2O3 and CaO
Authors:Daisuke Hirabayashi  Yoichi Sakai  Takeshi Yoshikawa  Kazuhiro Mochizuki  Yoshihiro Kojima  Kenzi Suzuki  Kazumasa Ohshita  Yasuo Watanabe
Institution:(1) EcoTopia Science Institute, Nagoya University, Nagoya 464-8603, Japan;(2) Department of Chemistry, Daido Institute of Technology, Nagoya 457-8530, Japan;(3) Crystals Division, Saint-Gobain K.K., Tokyo 102-0083, Japan
Abstract:Calcium ferrite oxides were prepared by calcining a mixture powder of iron- and calcium oxide. The 57Fe-Mössbauer spectra of the calcium ferrites oxides were measured, revealing that the products should be Ca2Fe2O5 and CaFe2O4, the ratio of which was dependent of the Fe/Ca atomic ratio of the mixture powder.
Keywords:calcium ferrite  Ca2Fe2O5            CaFe2O4            calcining of Fe2O3 and CaO            57Fe-M?ssbauer characterization
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