Absorption of Ni-centres in alkali chlorides |
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Authors: | Karel Polák |
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Institution: | 1. Institute of Solid State Physics, Czechoslovak Academy of Sciences, Prague
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Abstract: | Absorption spectra of Ni2+ doped NaCl, KCl, and RbCl were measured in the spectral range from 55,000 to 5,000 cm?1. The bands in the UV region are ascribed to the transition 3t 1u(σ, π)→3e g(σ) of NiCl6 complex ion. The connection of the intensity of charge transfer andd-d transitions has been discussed. |
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