Ionothermal synthesis of crystalline, condensed, graphitic carbon nitride |
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| Authors: | Bojdys Michael J Müller Jens-Oliver Antonietti Markus Thomas Arne |
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| Affiliation: | Max Planck Institute of Colloids and Interfaces, Research Campus Golm, Am Mühlenberg 1, 14476 Potsdam/Golm, Germany. |
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| Abstract: | Herein we report the synthesis of a crystalline graphitic carbon nitride, or g-C(3)N(4), obtained from the temperature-induced condensation of dicyandiamide (NH(2)C(=NH)NHCN) by using a salt melt of lithium chloride and potassium chloride as the solvent. The proposed crystal structure of this g-C(3)N(4) species is based on sheets of hexagonally arranged s-heptazine (C(6)N(7)) units that are held together by covalent bonds between C and N atoms which are stacked in a graphitic, staggered fashion, as corroborated by powder X-ray diffractometry and high-resolution transmission electron microscopy. |
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| Keywords: | carbon nitrides covalent frameworks layered compounds salt melt solid‐state structures |
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