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CONCURRENT SYNTHESIS OF METHANOL AND METHYL FORMATE CATALYZED BY COPPER-BASED CATALYSTS II.INFLUENCES OF SOLVENTS AND H2/CO MOLE RATIOS
Authors:Xingquan Liu  Yutang Wu  Shizhong Luo  Yingchun Yang  Zhaoxia Jia  Shunfen Li  Wenkai Chen  Zuolong Yu
Affiliation:Chengdu Institute of Organic Chemistry, The Chinese Academy of Sciences Chengdu, Sichuan 610041
Abstract:The concurrent synthesis of methanol and methyl formate (MF) from synthesis gas at low temperature and under low pressure in a slurry reactor has been investigated. The influences of the solvents and H2/CO mole ratios on the activity and methyl formate selectivity of CuCl and Cu-Cr oxide catalysts have been examined. The experimental results demonstrate that the solvents have remarkable influences on the activity and methyl formate selectivity of CuCl and Cu-Cr oxide catalysts.
Keywords:synthesis gas  methanol  methyl formate  Cu-based catalyst  synthesis  low temperature
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