Total synthesis of (+)-arteanniun M using the tandem oxy-Cope/ene reaction |
| |
| Authors: | Barriault L Deon D H |
| |
| Institution: | Department of Chemistry, University of Ottawa, 10 Marie Curie, Ottawa, Ontario, Canada, K1N 6N5. lbarriau@science.uottawa.ca |
| |
| Abstract: | see reaction]. The first total synthesis of (+)-arteannuin M was accomplished using the tandem oxy-Cope/transannular ene reaction as the key step to construct the bicyclic core of the natural product. The tandem reaction proceeded with high diastereo- and enantiomeric excess. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
