Pseudo-C(3)-symmetric tertiary alcohol building block via group-selective hydroalumination: a synthesis of (-)-malyngolide |
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Authors: | Suzuki T Ohmori K Suzuki K |
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Institution: | Department of Chemistry, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo 152-8551, Japan. |
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Abstract: | The stereocontrolled preparation of tertiary alcohol 4 and its TMS surrogate 5, which share a pseudo-C(3)()-symmetry, is described. Compound 4 was used for the synthesis of (-)-malyngolide. |
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