Structural, CV and IR spectroscopic evidences for preorientation in PET-active phthalimido carboxylic acids |
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| Authors: | Oelgemöller M Griesbeck A G Lex J Haeuseler A Schmittel M Niki M Hesek D Inoue Y |
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| Institution: | Inoue Photochirogenesis Project, ERATO, JST, 4-6-3 Kamishinden, Toyonaka-shi, Osaka 565-0085, Japan. |
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| Abstract: | Hydrogen bond and potassium cation mediated preorientation were detected for phthalimido acetic acid and the corresponding acetate. Evidence for these phenomena came from X-ray structure analysis as well as cyclic voltammetric and IR spectroscopic measurements. These interactions rationalize the photoinduced electron transfer (PET) reactivity of the substrates in photodecarboxylation reactions. |
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