Synthesis of conjugated diacetylene, metal-chelating monomers for polymerizable monolayer assemblies |
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Authors: | Roy B C Mallik S |
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Affiliation: | Department of Chemistry, North Dakota State University, Fargo, North Dakota 58105, USA. |
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Abstract: | [see structure]. Self-assembled monolayers (SAMs) of thiols on gold have been used for numerous applications. For protein targeting applications, one successful strategy is to use a metal-chelating SAM. It has also been demonstrated that polymerized SAMs are much more stable than non-polymerized counterparts. We report herein, the synthesis of several polymerizable, metal-chelating thiols capable of complexing luminescent lanthanide ions. |
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