Pyrolysis of 8,8-dimethyl-8-sila-2,3,4,5-tetrathiabicyclo[4.3.0]nonane |
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| Authors: | E. A. Chernyshev O. V. Kuz'min A. V. Lebedev V. G. Zaikin A. I. Mikaya |
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| Affiliation: | (1) A. V. Topchiev Institute of Petrochemical Synthesis, Academy of Sciences of the USSR, Moscow |
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| Abstract: | Conclusions The main products of the pyrolysis of 8,8-dimethyl-8-sila-2,3,4,5-tetrathiabicycIo-[4.3.0]nonane at 400 are 1,1-dimethylsilacyclopent-3-ene and 1,1-dimethyl-1-sila-2-thiacyclo-hexa-3, 5-diene, and at 600 carbon disulfide and thiophene; silacyclopentene is the sole reaction product, characteristic for the mass-spectrometric decomposition of the initial tetrasulfide.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No, 4, pp. 902–905, April, 1986. |
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