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检测硫酸氢根离子光化学探针分子研究进展
引用本文:李欠,邵士俊. 检测硫酸氢根离子光化学探针分子研究进展[J]. 分析化学, 2017, 45(8). DOI: 10.11895/j.issn.0253-3820.170098
作者姓名:李欠  邵士俊
作者单位:1. 甘肃农业大学,农学院,甘肃省干旱生境作物学重点实验室,植物生产类实验教学中心,兰州730070;2. 中国科学院兰州化学物理研究所,中国科学院西北特色植物资源化学重点实验室,甘肃省天然药物重点实验室,兰州730000
基金项目:国家自然科学基金,甘肃农业大学伏羲青年新秀引进人才项目资助,the National Natural Science Foundation of China
摘    要:酸氢根离子(HSO4)在生命、环境科学中发挥着非常重要的作用,进入环境后会污染环境,对人体造成危害.因此,选择性和高灵敏识别检测生物与环境样品中HSO4具有非常重要的意义.在众多的分析检测手段中,基于分子识别理念发展起来的光化学传感分子(探针)具有独特的优势.阴离子光化学传感体系以其选择性好、灵敏度高、易于实现在线分析,特别是可通过目视比色识别和原位检测等特点成为目前研究的热点.本文根据探针分子与HSO4之间的作用机理, 对近年来HSO4的光化学探针分子进行分类和总结,综述了HSO4光化学探针的研究进展,并对其应用前景与发展趋势进行了展望.

关 键 词:硫酸氢根  分子识别  比色识别  荧光探针  综述

Progress on Optical Probes for Hydrogen Sulfate Anion Sensing
LI Qian,SHAO Shi-Jun. Progress on Optical Probes for Hydrogen Sulfate Anion Sensing[J]. Chinese Journal of Analytical Chemistry, 2017, 45(8). DOI: 10.11895/j.issn.0253-3820.170098
Authors:LI Qian  SHAO Shi-Jun
Abstract:The hydrogen sulfate plays an important role in biological and environmental areas and can contaminate the environment, which will cause harm to human body.Thus it is of primary importance to detect hydrogen sulfate with high selectivity and sensitivity.Among these methods for detection of hydrogen sulfate, the optical chemosensor based on molecular recognition is desirable with unique advantage.Anions optical sensing systems are predominantly attractive due to their simplicity, high degree of specificity, low detection limits, easy on-line analysis and especial colorimetric recognition and in situ detection.Herein, the progress during the last decades of optical chemosensors and probes for hydrogen sulfate based on the recognizing mechanism is summarized.The further research orientations are also prospected.
Keywords:Hydrogen sulfate  Molecular recognition  Colorimetric recognition  Fluorescent probe  Review
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