Off-lattice Monte Carlo studies on size and shape of isolated polymer chains with isotactic and syndiotactic attached side groups |
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| Authors: | W Bruns L Vogel |
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| Institution: | (1) Present address: Iwan N. Stranski-Institut, Technische Universität Berlin, Deutschland;(2) Present address: Bundesanstalt für Materialprüfung, Berlin |
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| Abstract: | Chains containing side groups were generated with up to 102 bonds in the backbone for both iso- and syndiotactic arrangements. The mean-square end-to-end distance <h
2>, the mean-square radius of gyration <r
2> and the ratios <l
i
2
>/<l
1
2
> of the axes of inertia were investigated. It could be shown that the mean size and shape of such chains are not influenced by the kind of stereoregularity.Dedicated to Prof. Dr. K. Ueberreiter on the occasion of his 70th birthday. |
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| Keywords: | Perturbed chains Monte Carlo study end-to-end distance radius of gyration coil size axes of inertia coil shape |
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