Alkylation of perfluoro-2-methyl-2-pentylcarbanion with alkyl and allyl halides |
| |
| Institution: | 1. Shanghai Cancer Centre and Institutes of Biomedical Sciences, Fudan University, Shanghai 200032, PR China;2. Department of Chemistry, Fudan University, Shanghai 200433, PR China;1. Institute of Molecular Physics Polish Academy of Sciences, ul. M. Smoluchowskiego 17, 60-179 Poznań, Poland;2. Maria Curie-Skłodowska University, Department of Organic Chemistry, ul. Gliniana 33, 20-614 Lublin, Poland |
| |
| Abstract: | Perfluoro-2-methyl-2-pentylcarbanion, generated from perfluoro-4-methyl-2-pentene in an aprotic solvent, reacted with halides RX, where R = alkyl or allyl and X = I, Br, or Cl, to give fluorohydrocarbons of the general formula CF3CF2CF2C(CF3)2R. No reaction with iso-propyl iodide and with 1-iodo-2,2,2,-trifluoroethane occurred. The reaction with 1-iodo-3,3,3,-trifluoropropene resulted in the formation of 3,3,3,-trifluoropropene and 2-H-perfluoro-2-methyl-pentane. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
