The chemistry of diacyl peroxides - VIII. The reactions between polyfluorodiacyl peroxides and 2-nitro-2-nitrosopropane--Generation of bis(polyfluoroalkyl) nitroxides |
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| Affiliation: | 1. College of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, China;2. Research institute of QILU petrochemical company, SINOPEC, Zibo 255400, China;3. School of Chemical Engineering, Shandong University of Technology, Zibo 255049, China |
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| Abstract: | Thermal decomposition of 2-nitro-2-nitrosopropane (4) in F113 (CCl2F-CClF2) solution involves C-NO bond fission and forms acetone as the major product. In the presence of polyfluorodiacyl peroxide (3), the oxidation of 4 by 3 to 2,2-dinitropropane (5) is the predominant reaction and bis(polyfluoroalkyl) nitroxide(1) is generated as one of the by-products. |
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