Palladium-catalyzed allylic oxidation of 1-(p-toluenesulfonyl)-2-propene and 1-(trimethylsilyl)-1-(p-toluenesulfonyl)-2-propene |
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| Institution: | 1. Nanotechnology and Catalysis Research Center, 3rd Floor, Block A, Institute of Postgraduate Studies, University of Malaya, 50603 Kuala Lumpur, Malaysia;2. Environmental Research Laboratory, Department of Water and Environmental Engineering, School of Civil Engineering, Iran University of Science and Technology, 16765-163 Tehran, Iran |
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| Abstract: | The course of palladium-catalyzed oxidation of a terminal alkene by t-BuOOH or by O2/H2O is greatly modified when the allylic carbon bears a p-toluenesulfonyl substituent, and allylic oxidation results. Mechanistic explanations of this observation are proposed. |
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