Reactions of xenon difluoride. Part 6. Some reactions of phosphorus,arsenic and iodine compounds |
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| Affiliation: | 1. Shanghai University, Department of Chemistry, Shanghai 200444, China;2. Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800, China;1. NMR Research Centre, Indian Institute of Science, Bangalore 560012, India;2. Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore 560012, India;1. Department of Physics, Universiti Putra Malaysia, 43400, Serdang, Selangor, Malaysia;2. Department of Chemistry, Universiti Putra Malaysia, 43400, Serdang, Selangor, Malaysia;3. Department of Physics, Universiti Kebangsaan Malaysia, 43600, Bangi, Selangor, Malaysia;1. Institute of Chemistry, Siberian Division of Russian Academy of Sciences, 664033 Irkutsk, Russia;2. Department of Chemistry, Ben-Gurion University of the Negev, 84104 Beer Sheva, Israel;1. Dept. of Physics, JNTUCEA, Anantapuramu, Andhra Pradesh, India;2. Dept. of Physics, JNTUCEA, Anantapuramu, Andhra Pradesh, India;3. Dept. of Physics, GITAM Deemed to be University, Bangalore, Karnataka, India;4. Dept. of Applied Sciences, REVA University, Bangalore, Karnataka, India |
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| Abstract: | The reaction of XeF2 with some organo-phosphorus, -arsenic and-iodine compounds is described. The products were identified by fluorine nmr spectroscopy and the conditions under which fluorine exchange occurs were briefly investigated. Organoiodine (III) difluorides are suitable for the conversion of Ph2Te to Ph2TeF2; the decomposition of RIF2liberates IF and fluoroalkane. |
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