High-pressure vapor–liquid equilibria of systems containing ethylene glycol,water and methane: Experimental measurements and modeling |
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Authors: | Georgios K Folas Ole J Berg Even Solbraa Arne O Fredheim Georgios M Kontogeorgis Michael L Michelsen Erling H Stenby |
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Institution: | 1. Department of Chemical Engineering, Center for Phase Equilibria and Separation Processes (IVC-SEP), Technical University of Denmark, DK-2800 Lyngby, Denmark;2. Statoil ASA, Research and Development Center, N-7005 Trondheim, Norway |
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Abstract: | This work presents new experimental phase equilibrium measurements of the binary MEG–methane and the ternary MEG–water–methane system at low temperatures and high pressures which are of interest to applications related to natural gas processing. Emphasis is given to MEG and water solubility measurements in the gas phase. The CPA and SRK EoS, the latter using either conventional or EoS/GE mixing rules are used to predict the solubility of the heavy components in the gas phase. It is concluded that CPA and SRK using the Huron–Vidal mixing rule perform equally satisfactory, while CPA requires fewer interaction parameters. |
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Keywords: | CPA Cubic-Plus-Association equation of state ECR Elliott combining rule EoS equation of state GC&ndash MS gas chromatography mass spectrometer KF Karl&ndash Fisher titration MEG (mono)ethylene glycol NRTL non-random-two-liquid SRK Soave&ndash Redlich&ndash Kwong equation of state VLE vapor&ndash liquid equilibria |
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