Hydrogenation of 1,3-butadiene over magnesium oxide prepared by the decomposition of magnesium oxalate |
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| Authors: | Tsuneo Matsuda Keiko Ishimatsu Masatoshi Sugimoto |
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| Affiliation: | (1) Department of Applied Chemistry, Faculty of Engineering, Saitama University, 338 Urawa, Saitama, Japan |
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| Abstract: | In order to find the cause of the high activity for hydrogenation of 1,3-butadiene over a magnesium oxide catalyst prepared by thermal decomposition of magnesium oxalate, ESR and poisoning techniques were used. The cause of the high activity was attributed to large surface area and electron donating properties, which might be related to the surface basicity.
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