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Excess properties and vapor-liquid equilibrium data for the chloroform + tetrahydrofuran binary system at 30°C
Authors:Horacio N Sólimo  Ana C Gomez Marigliano
Institution:(1) It stituto de Física, Facultad de Ciencias Exactas y Tecnología, Universidad Nacional de Tucumán, Av. Independencia 1800, 4000 San Miguel de Tucumán, Argentina
Abstract:Excess molar volume, excess viscosity, excess molar enthalpy, and excess molar Gibbs free energy were calculated from the experimental density, viscosity, heat of mixing and vapor-liquid equilbrium data, respectively, for the chloroform + tetrahydrofuran system at 30°C over the complete molar fraction range. The results have been satisfactorily interpreted by assuming the existence of three species A, AB, and B in mutual equilibrium and that these species mix ideally. Values are given for the equilibrium constant and heat of formation of AB.
Keywords:Excess volume  excess enthalpy  excess viscosity  vaporliquid equilibria  chloroform-tetrahydrofuran mixture  ideal associated solution model
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