Reactions of N-alkylazinium cations. 3. Quaternary pteridinium salts. Synthesis,structure, and reactions with simple nucleophiles |
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Authors: | I V Kazantseva V N Charushin O N Chuapkhin A I Chernyshev S E Esipov |
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Institution: | (1) S. M. Kirov Ural Polytechnic Institute, 620002 Sverdlovsk |
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Abstract: | 4-Morpholinopteridine reacts with triethyloxonium tetra-fluoroborate to give two types of isomeric quaternary salts, viz., 1-ethyl- and 8-ethyl-4-morpholinopteridinium tetrafluoroborates. The structures of the pteridinium cations were proved by the 1H and 13C NMR spectra and also by chemical transformations in reactions with simple nucleophiles.See 1] for communication 2.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, pp. 1257–1264, September, 1985. |
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