Finite pulse width artifact suppression in spin-1 quadrupolar echo spectra by phase cycling |
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Authors: | Mananga E S Rumala Y S Boutis G S |
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Institution: | York College, The City University of New York, Department of Natural Sciences, Physics, 94-20 Guy R. Brewer Blvd., Jamaica, NY 11451, USA. |
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Abstract: | A phase cycling scheme for suppressing spectral artifacts introduced in quadrupolar echo spectroscopy of spin-1 nuclei due to finite pulse width effects is presented. The phase cycling scheme is developed using the formalism of average Hamiltonian theory and fictitious spin-1 operators. A simulation and experiment on deuterated polyethelene is performed highlighting the spectral artifact introduced by finite pulse widths and successful removal with the proposed phase cycling scheme. |
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Keywords: | Quadrupolar echo Finite pulse widths Deuterium NMR Phase cycling Average Hamiltonian theory |
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