Sulfur-containing derivatives of thiolan-1,1-dioxide 3. Reactions of salts of 2-(n,n-dialkyl)iminio-5,5-dioxoperhydrothieno[3,4-d]-1,3-dithiolans with bases

Salts of condensed 2-(N,N-dialkyl)iminio-1,3-dithiolan and 1,1-dioxothiolan rings are converted in alkaline media to 1,1-dioxothiolen esters of N,N-dialkyldithiocarbamic acids and into unsaturated bicyclic compounds. The latter are formed when the initial salts contain a bromine atom to the sulfonyl group.For Communication 2, see 1].Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 40–47, January, 1993.