首页 | 本学科首页   官方微博 | 高级检索  
     检索      

RELATIONSHIP BETWEEN Φ(z/l,X) RULE OF CHEMICAL PROCESSES IN SEAWATER AND HSAB PRINCIPLE——PRINCIPLE OF LEAST Σ AND CHEMICAL MODEL OF SEAWATER
引用本文:张正斌,刘莲生,陈镇东.RELATIONSHIP BETWEEN Φ(z/l,X) RULE OF CHEMICAL PROCESSES IN SEAWATER AND HSAB PRINCIPLE——PRINCIPLE OF LEAST Σ AND CHEMICAL MODEL OF SEAWATER[J].中国科学B辑(英文版),1983(6).
作者姓名:张正斌  刘莲生  陈镇东
作者单位:Department of Marine Chemistry,Shandong College of Oceanography,Qingdao,Department of Marine Chemistry,Shandong College of Oceanography,Qingdao,School of Oceanography,Oregon State University,U. S. A.
摘    要:This article reports on the application of the (z/l, X) rule of chemical processes in seawater to the study of the Principle of Hard and Soft Acids and Bases (HSAB). One result is the establishment of new scales of the hardness-softness of acids and bases which are more complete than those in the literature.Based on the principle of HSAB as well as abundant experimental data, we developed a new general principle of marine chemistry viz. the principle of least . Application of the principle of least has produced good results in the study of chemical model of the major constituents of seawater, the chemical speciation of trace elements, inorganic ion exchange reactions, the Irving-Williams aeries of transition elements, etc. Our investigations indicate that chemical models of the major constituents of seawater should take into consideration the formation of chloride ion pairs.

本文献已被 CNKI 等数据库收录!
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号