| Octopus Manganese Porphyrin with Polyglycol Chains as a Catalyst for the β-Selective Epoxidation of Cholesterol Derivatives |
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| 作者姓名： | RunHuaLI YuanCongZHAO[ JiangWU JingSongYOU XiaoQiYU |
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| 作者单位： | DepartmentofChemistry,SichuanUniversity,Chengdu610064 |
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| 摘 要： | Synthesis of a novel octopus porphyrin with polyglycol chains 1a was achieved. The catalytic activity of 1a‘s manganese complex for the epoxidation of cholesterol derivatives with PhIO give a satisfactory conversion and regioselectivity.
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| 关 键 词： | 章鱼卟啉 锰配合物 聚乙二醇 β-选择性环氧化作用 胆固醇衍生物 合成 催化剂 |
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