Stereoselective total synthesis of cryptopyranmoscatone A1 |
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| Authors: | Gowravaram Sabitha |
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| Affiliation: | Organic Division I, Indian Institute of Chemical Technology (CSIR), Hyderabad 500 607, India |
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| Abstract: | The first total synthesis of cryptopyranmoscatone A1 isolated from Cryptocarya moschata has been accomplished from 3,4,6-tri-O-acetyl-d-glucal. In addition to the RCM and cross-metathesis (CM) reactions, the synthesis features a highly diastereoselective Brown’s allylation reaction and sets the absolute stereochemistry of the natural product. |
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| Keywords: | Cryptopyranmoscatone oxa-Michael 3,4,6-Tri-O-acetyl- smallcaps" >d-glucal Cross-metathesis Brown&rsquo s allylation RCM |
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