A high-yield synthetic approach to trans-[Ir(ER3)2(CO)X] (ER3=PMe3, PEt3, PPhMe2, PPh2Me,P(OMe)3, AsMe3, AsEt3, AsPh3, SbPh3; X=Cl,Br) |
| |
| Affiliation: | 1. Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology, Daejeon 34141, Republic of Korea;2. Advanced Nanosensor Research Center, KI Nanocentury, Korea Advanced Institute of Science and Technology, Daejeon 34141, Republic of Korea;1. Berzelii Centre EXSELENT on Porous Materials, Department of Materials and Environmental Chemistry, Stockholm University, Stockholm, SE-10691, Sweden;2. Department of Chemistry, Assiut University, Assiut, 71515, Egypt;3. Department of Chemistry-Ångström Laboratory, Uppsala University, Box 532, SE 751 20, Uppsala, Sweden;4. Department of Organic Chemistry, Stockholm University, Stockholm, SE-10691, Sweden;5. Department of Nanotechnology, PORT Polish Center for Technology Development, 147 Stabłowicka Street, 54-066, Wrocław, Poland;2. Dow Chemical Company, Midland, MI 48667, USA;3. Department of Chemistry, University of Liverpool, Crown Street, Liverpool L69 7ZD, UK;4. Austin, TX, USA;1. Department of Chemistry, The Islamia University of Bahawalpur, Bahawalpur 63100, Pakistan;2. Department of Chemistry, University of Sahiwal, Sahiwal 57000, Pakistan;3. Institute for Advanced Study, Shenzhen University, Shenzhen 518060, PR China;4. Department of Physics, Jinan University, Guangzhou 510632, PR China;5. Department of Physics, COMSATS University Islamabad, Lahore Campus, Punjab, Lahore 54000, Pakistan;6. Hefei National Laboratory for Physical Sciences at the Microscale, CAS Key Laboratory of Soft Matter Chemistry, Department of Chemistry, University of Science and Technology of China, Hefei, Anhui, 230026 PR China;7. School of Chemistry and Chemical Engineering, Beijing Institute of Technology, 5# Zhongguancun Road, Haidian District, Beijing 100081, PR China;8. School of Materials Science and Engineering, Jiangsu University, Zhenjiang 212013, PR China;1. Institute of Electrochemistry, University of Alicante, E-03080 Alicante, Spain;2. Institute of Chemistry, University of Tartu, 50411 Tartu, Estonia;3. Department of Chemistry and Biotechnology, Tallinn University of Technology, 12618 Tallinn, Estonia;4. Institute of Ecology and Earth Sciences, University of Tartu, 50411 Tartu, Estonia;5. Institute of Physics, University of Tartu, 50411 Tartu, Estonia |
| |
| Abstract: | The complex [Ir(CO)2X2][NBu4] (X=Cl, Br) forms Vaska-type complexes, trans-[Ir(ER3)2(CO)X], when treated with two equivalents of aryl- or alkyl-phosphines, arsines, or stibines under a CO atmosphere. The synthesis is general for a wide range of phosphines, arsines, or stibines irrespective of the cone angle. For small cone-angle ligands, the initial addition of ligand to [Ir(CO)2X2][NBu4] is performed at low temperature. The synthesis and characterisation of three new Vaska-type complexes trans-[Ir(P(OMe)3)2(CO)Cl], trans-[Ir(AsMe3)2(CO)Cl], and trans-[Ir(AsEt3)2(CO)Cl] is also reported. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
