Synthesis,crystal structure and properties of manganese(II) hexafluoroacetylacetonates Mn(hfa)2(H2O)2 and KMn(hfa)3 |
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| Institution: | 1. Department of Chemistry, Lomonosov Moscow State University, 119991 Moscow, Russia;2. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky Prospect 47, 119991 Moscow, Russia |
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| Abstract: | Two manganese(II) hexafluoroacetylacetonate complexes, dihydrate, the Mn(hfa)2(H2O)2 (1), and the bimetallic KMn(hfa)3 (2) have been synthesized and characterized by X-ray single crystal structure analysis. They have a molecular structure and a polymeric structure, respectively. The high stability of 2 allowed sublimation without decomposition. It was then used as a precursor for MOCVD of fluoroperovskite, KMnF3. |
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