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Synthesis and coordination chemistry of tetrabutyldithioimidodiphosphinates |
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| Institution: | 1. Université Côte d''Azur, CNRS, INSERM, Institut de Biologie Valrose (iBV), Nice 06108, France;2. Faculty of Biochemistry and Molecular Medicine, University of Oulu, Oulu FI-90014, Finland;3. Faculty of Medicine, Research Unit of Biomedicine, University of Oulu, Oulu FI-90014, Finland;4. Foundation for the Finnish Cancer Institute, Tukholmankatu 8, Helsinki, Finland;1. Indian Institute of Management, Prabandh Nagar, Lucknow, India;2. Indian Institute of Technology, Roorkee, India;3. Indian Institute of Management, Prabandh Shikhar, Indore, India |
| Abstract: | Butyl substituted imidodithiophosphinates R2P(S)NP (S)R′2 (R=nBuiBusBuR′=nBuiBusBu) have been synthesised via an HBr elimination reaction between R2P(S)NH2 and R′2P(S)Br The compounds were characterised spectroscopically Crystallographic and spectroscopic studies reveal nBu2P(S)NHP(S)nBu2 and sBu2P(S)NHP(S)iBu2 to be hydrogen bonded transoid dimers and iBu2P(S)NHP(S)iBu2 to be a transoid hydrogen bonded chain Reactions of the imidodithiophosphinates with ZnCl2 or MCl2COD gave the coordination complexes MR2P(S)NP (S)R′2]2 (R=nBuiBusBuR′=nBuiBusBuM=ZnPd: R=nBuiBusBuPt). |
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