Raman Analysis of Polymerization of APST Molecule |
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| Authors: | Iva Movre Šapić Vesna Volovšek Krešimir Furić Lahorija Bistričić Vladimir Dananić |
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| Affiliation: | 1. Faculty of Chemical Engineering and Technology, University of Zagreb, Marulićev trg 19, 10000 Zagreb, Croatia;2. Ruđer Bošković Institute, Bijenička cesta 54, 10000 Zagreb, Croatia;3. Faculty of Electrical Engineering and Computing, University of Zagreb, Unska 3, 10000 Zagreb, Croatia |
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| Abstract: | In this work we investigated the solidification of aminopropylsilanetriol dissolved in water (∼25%) under different conditions by Raman spectroscopy. The solidification was carried out at three different temperatures 8 °C, 23 °C and 60 °C. The influence of electromagnetic radiation on the polymerization process was also studied. Samples were held to solidify in dark and at UV (254 nm and 356nm) spectral range. In order to investigate the influence of the substrate on the resulting polymer structure, teflon, PVC, glass, brass and silica were used. Best ordered polymerized structure was achieved for samples deposited on plastics and solidified in dark, at room temperature. |
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| Keywords: | aminopropylsilanetriol gauche conformers ladder structure polymerization trans |
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