Chalcogenolato-di-thiocarbamato-complexes of zinc: The X-ray single crystal structures of pyridine adducts |
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Affiliation: | 1. Materials Chemistry and Metal Fuel Cycle Group, Indira Gandhi Centre for Atomic Research, Kalpakkam 603 102, Tamil Nadu, India;2. Homi Bhabha National Institute, Indira Gandhi Centre for Atomic Research, Kalpakkam 603 102, Tamil Nadu, India;2. School of Mechanical Engineering, WCU Nano Research Center, Yeungnam University, Gyeongsan 712-749, South Korea;3. Department of Chemistry, Faculty of Science, University of Qom, PO Box 37185-359, Qom, Iran |
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Abstract: | Novel mixed complexes 2,4,6-Me3C6H2SZnS2CNEt2 (1), 2,4,6-Me3C6H2SeZnSe2CNEt2 (2) and their pyridine adducts ([Zn(SC6H2Me3-2,4,6)2(C5H5N)2] (3), [Zn(SeC6H2Me3-2,4,6)2(C5H5N)2] (4) and (Et2CNSe2)2Zn.NC5H5 (5) and (Et2CNS2)2Zn.NC5H5 (6) have been synthesised and characterised. The X-ray single crystal structures of (4), (5) and (6) have been determined. |
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