Synthesis and crystal structure of ZnPhen(i-Pr2NCS2)2 and molecule packing types in complexes ZnPhen(R2NCS2)2 (R=Me,Et, i-Pr,n-Pr,i-Bu,n-Bu) |
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| Affiliation: | 1. Department of Chemistry, Annamalai University, Annamalainagar 608 002, Tamil Nadu, India;2. Centro di Cristallografia Strutturale, Polo Scientifio di Sesto Fiorentino, Via della Lastruccia No. 3, 50019 Sesto Fiorentino, Firenze, Italy;1. Department of Chemistry, Payame Noor University, PO Box 19395-4697, Tehran, Iran;2. Department of Chemistry,Yadegar-e-Imam Khomeini (RAH) Branch, Islamic Azad University, Tehran, Iran;3. Department of Chemistry, Buali University, Hamedan, Iran;1. Department of Crystallography, Institute of Chemistry, University of Silesia, 9th Szkolna St., 40-006 Katowice, Poland;2. Department of X-ray Crystallography and Crystal Chemistry, Institute of General and Ecological Chemistry, Lodz University of Technology, 116 Żeromski St., 90-924 Łódź, Poland;1. School of Chemistry, Damghan University, Damghan 36715-364, Iran;2. Department of Chemistry, Ferdowsi University of Mashhad, Mashhad 91775-1436, Iran |
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| Abstract: | A novel mixed-ligand complex ZnPhen(i-Pr2NCS2)2 has been synthesized and its single crystals grown. We have determined its crystal structure from X-ray diffraction data. The structure consists of monomeric molecules; a zinc atom surrounded by two nitrogen and four sulfur atoms making a distorted octahedron. Various packing modes of molecules forming isolated ‘dimers’, ribbons (chains), columns and layers have emerged from the study of the spatial molecule arrangement in the complexes ZnPhen(R2NCS2)2 (R=Me, Et, i-Pr, n-Pr, i-Bu, n-Bu). The interactions between the Phen molecules have also been studied for these complexes. |
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