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Excess molar enthalpies for binary mixtures of trimethyl phosphate with alkanols {CH3(CH2)nOH, n = 0–3} at 298.15 K |
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| Authors: | Kaiyu Liu Jinfeng Xu Shijun Liu Qiyuan Chen Zhongliang Xiao Daowu Yang |
| Affiliation: | aCollege of Chemistry and Chemical Engineering, Central South University, Changsha, 410083 Hunan, China bCollege of Chemistry and Environmental engineering, Changsha University of Science & Technology, Changsha, 410076 Hunan, China |
| Abstract: | The excess molar enthalpies () for the binary mixtures of trimethyl phosphate (TMP) with alkanols {CH3(CH2)nOH, n = 0–3} have been measured with an isothermal calorimeter at 298.15 K and atmospheric pressure. The values are positive for all the mixtures over the whole composition range. The values increase in the order methanol < ethanol < 1-propanol < 1-butanol. The experimental results have been correlated with the Redlich–Kister equation. |
| Keywords: | Excess molar enthalpy Trimethyl phosphate Alkanols |
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