Influence of Substance on the Equilibrium Translation Rate for the Isothermal and Isobaric Chemical Reactions of Ideal gases期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Influence of Substance on the Equilibrium Translation Rate for the Isothermal and Isobaric Chemical Reactions of Ideal gases

Authors:	Zhang Shimin

Affiliation:	(1) College of Chemistry & Chemical Engineering, Central South University, Changsha, Hunan, China

Abstract:	To increase inert substance i will make the equilibrium translation rate α_j of reactant j decrease if ∑_i ν_i < 0 or increase if ∑_i ν_i > 0. When ${nu_i} big/ {sum_i {nu_i}},<,0$ or ${nu_i} big/ {sum_i {nu_i}}geqslant 1$ , to increase non-inert substance i will make α_j increase if i is reactant (i ≠ j) or decrease if i is resultant. When $x_i^0 ,=,{nu_i} big/ {sum_i {nu_i} }, alpha_j$ has maximum if i is reactant (i≠ j) or minimum if i is resultant. If i is reactant, $x_i^0 ={nu_i} big/ {sum_i {nu_i}} ,>,x_r^0 ={left\| {nu_r} right\|} big/{sum_r {left\| {nu_r} right\|}}$ (x _r⁰ is “optimum proportion” of reactant)

Keywords:	equilibrium translation rate ideal gases isobaric reactions optimum proportion
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