Thermodynamics of binary mixtures of molecular and noble gases |
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Authors: | G. M. Kremer L. Kai W. Marques Jr. |
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Affiliation: | (1) Departamento de Física, Universidade Federal do Paraná, Caixa Postal 19091, 81531 Curitiba, Brazil;(2) Hermann Föttinger Institut, TU Berlin, W-1000 Berlin 12, FRG |
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Abstract: | A theory based on rational thermodynamics and statistical mechanics for a binary mixture of a noble gas and a molecular gas with vibrating molecules is developed. The problem concerning the propagation of plane harmonic waves of small amplitudes is investigated in the limit of low frequencies. Constitutive equations for a linear irreversible thermodynamic theory and the Onsager relations are also analyzed. |
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