Asymmetric organocatalytic diboration of alkenes |
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| Authors: | Amadeu Bonet Cristina Sole Henrik Gulyás Elena Fernández |
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| Affiliation: | Dept. Química Física i Inorgànica, University Rovira i Virgili, C/Marcel·lí Domingo s/n, 43007 Tarragona, Spain. mariaelena.fernandez@urv.cat. |
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| Abstract: | The use of chiral alcohols to form the Lewis acid-base *RO(-)→ bis(pinacolato)diboron adduct, in situ, provides an opportunity to induce asymmetry in the organocatalytic diboration of alkenes and complements the well established transition metal-mediated enantioselective diboration. |
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