The facile reduction of carbon dioxide to carbon monoxide with an amido-digermyne |
| |
| Authors: | Jiaye Li Markus Hermann Gernot Frenking Cameron Jones |
| |
| Affiliation: | School of Chemistry, Monash University, PO Box 23, Melbourne, VIC, 3800 (Australia). |
| |
| Abstract: | Taking the fizz out: A digermyne compound with a Ge?Ge single bond has been shown to quantitatively reduce CO(2) to CO at temperatures as low as -40?°C. The mechanism of this unprecedented reaction has been probed by spectroscopic and computational techniques and involves a metastable intermediate (see picture; Ar*=C(6) H(2) {C(H)Ph(2) }(2) Me-2,6,4). |
| |
| Keywords: | carbon dioxide density functional calculations germanium green chemistry reduction |
| 本文献已被 PubMed 等数据库收录！ |
|
