103Rh, 17O,and 31P NMR study of Rh(III) complex formation in acidic sulfate-phosphate media |
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| Authors: | A. V. Belyaev S. N. Vorob’eva M. A. Fedotov |
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| Affiliation: | 1.Nikolaev Institute of Inorganic Chemistry,Russian Academy of Sciences,Novosibirsk,Russia;2.Boreskov Institute of Catalysis,Russian Academy of Sciences,Novosibirsk,Russia |
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| Abstract: | Rhodium(III) complex formation with phosphoric acid in strong acidic solutions has been studied by 103Rh, 17O, and 31P NMR. Phosphoric acid is mainly coordinated to rhodium as a monodentate terminal HPO42− ion, while the coordinated phosphate ion accounts for no more than 7%. |
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