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Refinement of taking into account molecule sizes in the lattice gas model
Authors:Yu. K. Tovbin
Abstract:An approach to consideration of non-integer ratios between linear molecule sizes having shapes close to linear chains, plates, and rectangular parallelepipeds was suggested for the lattice gas model. A statistical description of molecule orientation states retains spatial discretization as for molecules with multiple ratios between linear molecule sides, but the general balance of filled nodes and, which is most important, the influence of interparticle potentials reflects real molecule sizes through the nonideality function.
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