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Bi-induced vibrational modes in GaAsBi
Authors:M.J. Seong   S. Francoeur   S. Yoon   A. Mascarenhas   S. Tixier   M. Adamcyk  T. Tiedje
Affiliation:aNational Renewable Energy Laboratory, 1617 Cole Boulevard, Golden, CO 80401, USA;bAMPEL, Department of Physics and Astronomy, University of British Columbia, Vancouver, BC V6T 1Z4, Canada;cDepartment of Physics, Chung-Ang University, Seoul 156-756, Republic of Korea;dDivision of Nano Sciences and Department of Physics, Ewha Womans University, Seoul 120-750, Republic of Korea
Abstract:We have studied GaAs1−xBix (up to x3%) using Raman scattering with two different polarization configurations. Two Bi-induced phonon modes are observed at 186 cm−1 and 214 cm−1 with increasing Raman intensity as the Bi concentration increases. By comparing Raman selection rules for the observed Bi-induced phonon modes with those for the substitutional N vibrational mode (GaN mode) in GaAsN, the phonon mode at 214 cm−1 is identified as originating from substitutional Bi at the As site in GaAsBi.
Keywords:Isoelectronic impurity   GaAsBi   Raman scattering   Phonon
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