Photolysis of tris(trimethylsilyl)-phenylsilane in alcohols: A consecutive generation of sililene species |
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| Authors: | Kunio Oka Ren Nakao |
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| Institution: | 1. Osaka Prefectural Radiation Research Institute, 174-l6 Shinke-cno, 593, Sakai, Osaka, Japan
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| Abstract: | Photolysis of tris(trimethylsilyl)phenylsilane, in alcohols yielded 1-aikoxy-1-phenyl-2, 2,2-trimethyldisilane, dialkoxyphenylsilane, hexamethyldistlane, and trimethylstlane as major products. The formation of the products was explained by a mechanssm which included the consecutive generatinn of phenyltrimethylsilylsilyleses and alkoxyphenylsilylenes. |
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