| 纳米限域体系的催化特性 |
| |
| 引用本文： | 包信和.纳米限域体系的催化特性[J].中国科学B辑,2009,39(10):1125-1133. |
| |
| 作者姓名： | 包信和 |
| |
| 作者单位： | 催化基础国家重点实验室, 中国科学院大连化学物理研究所, 大连 116023 |
| |
| 基金项目： | 致谢 作者感谢中国科学院大连化物研究所潘秀莲博士、马丁研究员等的有益讨论和石英女士在文章准备中的帮助;感谢国家重点基础研究发展计划项目（编号：G1999022400,2005CB221400）和国家自然科学基金重大项目（批准号：90206036）经费的资助. |
| |
| 摘 要： | 本文以限域体系对电子调控为基础和出发点,系统介绍体系尺寸变化导致催化特性调控的实验和理论研究结果,通过纳米银催化选择氧化和碳管限域的纳米粒子高效催化合成气转化等实例进一步阐述基于限域效应的催化＂尺度调控法＂的概念.
|
| 关 键 词： | 限域体系 催化 纳米管 合成气转化 |
| 收稿时间： | 2009-09-10 |
| 修稿时间： | 2009-09-14 |
Catalytic characters of the nano-confined systems |
| |
| BAO XinHe.Catalytic characters of the nano-confined systems[J].Science in China(Series B),2009,39(10):1125-1133. |
| |
| Authors: | BAO XinHe |
| |
| Institution: | BAO XinHe (State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, the Chinese Academy of Sciences, Dalian 116023, China) |
| |
| Abstract: | In the present work, the unique characters of the nano-confined systems for catalysis are demonstrated. The emphasis is on the synergetic effects of the electron confinements derived from the nano-particle and the carbon nanotube channels, as well as the nano-layers with subsurface metals. The catalytic reactions, such as the selective oxidation and the conversion of syngas, have been employed to illustrate the novel concept of size-modulating in catalysis. |
| |
| Keywords: | catalysis Nano-confined carbon nanotubes syngas conversion |
| 本文献已被 维普 等数据库收录！ |
| 点击此处可从《中国科学B辑》浏览原始摘要信息 |
| 点击此处可从《中国科学B辑》下载免费的PDF全文 |
