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Synthesis of chrysenosiloles via Mallory photocyclization |
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| Authors: | Qi Yang Kunbing Ouyang Zhenfeng Xi | |
| Institution: | 1. Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing, 100871, China;2. Hunan Province Key Laboratory of Green Organic Synthesis and Application, Key Laboratory of Environmentally Friendly Chemistry and Application of Ministry of Education, College of Chemistry, Xiangtan University, Xiangtan, 411105, China;3. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, CAS, Shanghai, 200032, China | |
| Abstract: | Development of synthetic methods for silole-containing or –fused polycyclic aromatic compounds has been in great demand. Described in this paper is an easy synthetic method for the high-efficient synthesis of chrysenosilole derivatives from silatricyclic compounds via the Mallory photocyclization reaction. It is noteworthy that those conventional transition-metal and Lewis acid catalyzed or mediated C | |
| Keywords: | Mallory photocyclization Silole derivatives Chrysenosilole derivative Polycyclic aromatic compounds Aryl-aryl C C bond coupling π-Conjugated organic materials | |
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