Adsorption of cobalt ions on the "electrolytic solution/gamma-alumina" interface studied by diffuse reflectance spectroscopy (DRS)

Diffuse reflectance spectroscopy was used for the first time to investigate the adsorption of the [Co(H2O)6]2+ ions on the interface developed between the surface of the gamma-alumina particles and the electrolytic aqueous solutions used for the preparation of cobalt-supported gamma-alumina catalysts by equilibrium deposition filtration. The formation of inner-sphere Co(II) surface complexes in which Co(II) is in octahedral symmetry was confirmed. A deconvolution peak centered at approximately 585 nm was attributed to the exchange of one aqua ligand with one AlxOHy (x = 1, 2, or 3; y = 0 or 1) negatively charged surface group resulting in the formation of mononuclear monosubstituted inner-sphere Co(II) complexes at a Co(II) surface concentration equal to 0.02 micromol of Co(II)/m2. It was inferred that as the surface Co(II) concentration increases the formation of disubstituted and/or trisubstituted surface complexes is favored with respect to the formation of monosubstituted Co(II) surface complexes. A deconvolution peak centered at approximately 640 nm was attributed to the exchange of one or more aqua ligands with bridging hydroxo ligands (Co-O-H). The relative magnitude of this peak increases with the Co(II) surface concentration, reflecting the increasing formation of binuclear, oligonuclear, and multinuclear Co(II) surface complexes and then the formation of the Co(II) surface precipitate.