| Click反应和多氮化合物手性催化剂 |
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| 引用本文： | 王乃兴.Click反应和多氮化合物手性催化剂[J].有机化学,2008,28(3):361-366. |
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| 作者姓名： | 王乃兴 |
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| 作者单位： | 中国科学院理化技术研究所,北京,100080 |
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| 基金项目： | 国家自然科学基金，总装备部专项基金 |
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| 摘 要： | Click化学涉及一系列能够在温和条件下高产率进行的有机反应, 已经被用来构建一些手性有机催化剂. 一些多氮化合物作为手性有机催化剂, 在反应过程中形成多重氢键使反应过渡态得以稳定, 显示出非常好的立体选择性.
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| 关 键 词： | Click化学 手性有机催化剂 立体选择性 |
| 收稿时间： | 2006-12-26 |
| 修稿时间： | 2007-07-10 |
Click Reactions and Asymmetric Organocatalysts of Polynitrogen Compounds |
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| WANG Nai-Xing.Click Reactions and Asymmetric Organocatalysts of Polynitrogen Compounds[J].Chinese Journal of Organic Chemistry,2008,28(3):361-366. |
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| Authors: | WANG Nai-Xing |
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| Institution: | (Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100080) |
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| Abstract: | Click chemistry includes a range of reactions that proceed in high yield under ambient conditions and has been employed to construct some asymmetric organocatalysts. Some asymmetric organocatalysts of polynitrogen compounds are shown to construct stable transition states by extensive H-bonded networks, and good stereoselective reactions are shown by these asymmetric organocatalysts |
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| Keywords: | click chemistry chiral organicatalyst stereoselectivity |
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